Walking on Thin Ice
Ice is water, frozen into a solid state. Depending on the presence of impurities such as particles of soil or bubbles of air, it can appear transparent or a more or less opaque bluish-white color.
In the Solar System, ice is abundant and occurs naturally from as close to the Sun as Mercury to as far as the Oort cloud. Beyond the Solar System, it occurs as interstellar ice. It is abundant on Earth's surface – particularly in the polar regions and above the snow line – and, as a common form of precipitation and deposition, plays a key role in Earth's water cycle and climate. It falls as snowflakes and hail or occurs as frost, icicles or ice spikes.
Ice molecules can exhibit up to sixteen different phases (packing geometries) that depend on temperature and pressure. When water is cooled rapidly (quenching), up to three different types of amorphous ice can form depending on the history of its pressure and temperature. When cooled slowly correlated proton tunneling occurs below 20 K giving rise to macroscopic quantum phenomena. Virtually all the ice on Earth's surface and in its atmosphere is of a hexagonal crystalline structure denoted as ice Ih (spoken as "ice one h") with minute traces of cubic ice denoted as ice Ic. The most common phase transition to ice Ih occurs when liquid water is cooled below 0°C (273.15K, 32°F) at standard atmospheric pressure. It may also be deposited directly by water vapor, as happens in the formation of frost. The transition from ice to water is melting and from ice directly to water vapor is sublimation.
As a naturally-occurring crystalline inorganic solid with an ordered structure, ice is considered a mineral. It possesses a regular crystalline structure based on the molecule of water, which consists of a single oxygen atom covalently bonded to two hydrogen atoms, or H-O-H. However, many of the physical properties of water and ice are controlled by the formation of hydrogen bonds between adjacent oxygen and hydrogen atoms; while it is a weak bond, it is nonetheless critical in controlling the structure of both water and ice.
“ice contains no future , just the past, sealed away. As if they're alive, everything in the world is sealed up inside, clear and distinct. Ice can preserve all kinds of things that way- cleanly, clearly. That's the essence of ice, the role it plays.” ― Haruki Murakami
An unusual property of ice frozen at atmospheric pressure is that the solid is approximately 8.3% less dense than liquid water. The density of ice is 0.9167 g/cm3 at 0 °C, whereas water has a density of 0.9998 g/cm³ at the same temperature. Liquid water is densest, essentially 1.00 g/cm³, at 4 °C and becomes less dense as the water molecules begin to form the hexagonal crystals of ice as the freezing point is reached. This is due to hydrogen bonding dominating the intermolecular forces, which results in a packing of molecules less compact in the solid. Density of ice increases slightly with decreasing temperature and has a value of 0.9340 g/cm³ at −180 °C (93 K).
When water freezes, it increases in volume (about 9% for freshwater). The effect of expansion during freezing can be dramatic, and ice expansion is a basic cause of freeze-thaw weathering of rock in nature and damage to building foundations and roadways from frost heaving. It is also a common cause of the flooding of houses when water pipes burst due to the pressure of expanding water when it freezes.
The result of this process is that ice (in its most common form) floats on liquid water, which is an important feature in Earth's biosphere. It has been argued that without this property, natural bodies of water would freeze, in some cases permanently, from the bottom up, resulting in a loss of bottom-dependent animal and plant life in fresh and sea water. Sufficiently thin ice sheets allow light to pass through while protecting the underside from short-term weather extremes such as wind chill. This creates a sheltered environment for bacterial and algal colonies. When sea water freezes, the ice is riddled with brine-filled channels which sustain sympagic organisms such as bacteria, algae, copepods and annelids, which in turn provide food for animals such as krill and specialised fish like the bald notothen, fed upon in turn by larger animals such as emperor penguins and minke whales.
When ice melts, it absorbs as much energy as it would take to heat an equivalent mass of water by 80 °C. During the melting process, the temperature remains constant at 0 °C. While melting, any energy added breaks the hydrogen bonds between ice (water) molecules. Energy becomes available to increase the thermal energy (temperature) only after enough hydrogen bonds are broken that the ice can be considered liquid water. The amount of energy consumed in breaking hydrogen bonds in the transition from ice to water is known as the heat of fusion.
“If you are going to walk on thin ice, you might as well dance”
As with water, ice absorbs light at the red end of the spectrum preferentially as the result of an overtone of an oxygen-hydrogen (O-H) bond stretch. Compared with water, this absorption is shifted toward slightly lower energies. Thus, ice appears blue, with a slightly greener tint than for liquid water. Since absorption is cumulative, the color effect intensifies with increasing thickness or if internal reflections cause the light to take a longer path through the ice.
Other colors can appear in the presence of light absorbing impurities, where the impurity is dictating the color rather than the ice itself. For instance, icebergs containing impurities (e.g., sediments, algae, air bubbles) can appear brown, grey or green.